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Principles of Physical Chemistry, by Hans Kuhn, Horst-Dieter Försterling, David H. Waldeck
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Principles of Physical Chemistry, Second Edition uniquely uses simple physical models as well as rigorous treatments for understanding molecular and supramolecular systems and processes. In this way the presentation assists students in developing an intuitive understanding of the subjects as well as skill in quantitative manipulations. The unifying nature of physical chemistry is emphasized in the book by its organization - beginning with atoms and molecules, and proceeding to molecular assemblies of increasing complexity, ending with the emergence of matter that carries information, i.e. the origin of life, a physicochemical process of unique importance. The aim is to show the broad scope and coherence of physical chemistry.
- Sales Rank: #1116500 in Books
- Published on: 2009-03-17
- Original language: English
- Number of items: 1
- Dimensions: 10.30" h x 2.78" w x 7.05" l, 3.95 pounds
- Binding: Hardcover
- 1084 pages
Review
"The book has clear pedagogical intentions: the authors aim to provide a global scientific methodology for the comprehension of chemical systems at different length scales, solidly based on general principles." (Bunsenmagazine, 1 November 2010)
Recommended. Upper-division undergraduate through professional collections". (Choice, 1 November 2010)
From the Back Cover
"This admirable text provides a solid foundation in the fundamentals of physical chemistry including quantum mechanics and statistical mechanics/thermodynamics. The presentation assists the students in developing an intuitive understanding of the subjects as well as skill in quantitative manipulations. Particularly exciting is the treatment of larger molecular systems. With a firm but gentle hand, the student is led to several organized molecular assemblies including supramolecular systems and models of the origin of life. By learning of some of the most productive areas of current chemical research, the student may see the discipline as an active, young science in addition to its many accomplishments of earlier years. This text makes physical chemistry fun and demonstrates why so many find it a stimulating and rewarding profession."
—Edel Wasserman, President (1999) of the American Chemical Society, regarding the first edition of this book.
Takes readers from atoms to increasingly complex molecular assemblies to the emergence of life
Principles of Physical Chemistry presents a novel approach to physical chemistry that emphasizes the use of a few fundamental principles to quantitatively describe the nature of molecules and their assemblies. It begins with atoms and molecules, using the electron-in-a-box model to illustrate the essential features of quantum mechanics and why atoms and molecules exist. Thermodynamics is not introduced in the classical manner, considering the first and second law as postulates, but approached by studying assemblies of molecules statistically. The authors proceed to molecular assemblies of increasing complexity, evolving from ideal gases to real gases and solutions, then to macromolecules and supramolecular machines, and ending with the search for the logical conditions and chemical requirements for physicochemical processes leading to life's origin, the emergence of matter that carries information. This text is ideal for both undergraduate and graduate courses in physical chemistry, providing a basis for understanding the nature of chemical processes in biology, chemistry, and engineering.
Principles of Physical Chemistry examines several important topics that are often overlooked, yet are critical to a full understanding of the field, including:
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Macromolecules
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Principles of organized molecular assemblies
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Construction of supramolecular machines
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Basic mechanisms in the emergence of information producing and carrying forms of matter
Throughout the text, actual experimental data are used to help readers understand the practical implications of theoretical developments. Simple physical models and examples are used to explain molecular and supramolecular systems and processes. The CD-ROM packaged with the text offers problems, exercises, interactive Mathcad exercises and data tables with search functions that enable readers to apply their newfound skills and knowledge to solving actual problems. In addition, the CD contains Foundations and Justifications, in which mathematical proofs and derivations are presented.
About the Author
HANS KUHN, Dr. phil, became a Professor at the University of Basel in 1951. From 1953–1970 he was on the chair of the Institute of Physical Chemistry at the Philipps-University at Marburg, and in 1970 he became Director at the Max Planck Institute for Biophysical Chemistry (Karl-Friedrich-Bonhoeffer-Institut) until he retired in 1985. Professor Kuhn has published papers in such fields as polymer science, quantum chemistry, organized molecular assemblies, and the origin of life.
HORST-DIETER FÖRSTERLING, Dr. phil., was a Professor in the Department of Physical Chemistry at the Philipps-University of Marburg from 1972 until his retirement in 1999. Professor Försterling has taught physical chemistry courses and laboratory courses at all levels, including graduate and advanced graduate courses in spectroscopy, statistical mechanics, reaction kinetics, and quantum mechanics. His research interests include quantum chemistry, reaction mechanisms, oscillating chemical reactions, and chemical waves.
DAVID H. WALDECK, PhD, is Professor and Chair in the Department of Chemistry at the University of Pittsburgh. Professor Waldeck has taught chemistry courses at all levels, including graduate and advanced graduate courses in statistical mechanics, reaction dynamics, and quantum mechanics. His research interests include condensed-phase reaction dynamics (homogeneous and heterogeneous), solute-solvent interactions (structural and dynamical characteristics), relaxation processes in solids, and electron transport at the nanometer scale.
Most helpful customer reviews
16 of 16 people found the following review helpful.
The first fully coherent, continuous and truly modern text!
By Giovani Bassi
By Giovani_Bassi@Hotmail.com
This book is really, really new in its disposition. I admire that someone still has courage to follow his (or hers) own ideas, instead of just going with established trends, that are not necessarily very good. The authors are brilliant scientists, and the sharpness of their intellects and their passion is with you all the time. I must again be very brief, but can give the following comments on this masterpiece:
- The authors accomplish "the impossible": the book allows the reader to refer to individual chapters - as reference, then, thanks to very lucid, simple mathematical derivations, always with the weaknesses in the models used clearly defined - as well as to read the entire book and "survive" - i.e. understand what one is reading - without using any other sources parallel.
- The authors start with defining the few q.m. notions, very simply and lucidly, that are then used throughout the book (modern as it is!), rather than using the archaic introduction comprised of abstract classical-thermodynamic discussions, that set out to uselessly "reinvent the wheel", by refusing to take help of the fact that we know about the discontinuity of matter (i e atoms). No more q.m. is presented than that which is needed in the rest of the book, otherwise a great danger to coherence, in my opinion (a disesase of most modern "phone-directory texts"). And this is typical of the book: no more is introduced than that which is needed - and then, those concepts are used throughout, afterwards, which is wonderful for the user: it both lets him experince control and also is the best sort of review, to actually use the concepts learned.
- Almost every theory presented is immediately afterwards applied to actual, down-to-earth chemistry, always involving familiar undergraduate topics, mostly from organic and biochemistry. Again, this is valuable as review for this courses and further reflection. Note that the examples are always VERY, VERY INTERESTING.
- As indicated, the book presents one whole, unified view, and what will be to the immense joy of all students, these authors point out, carefully, whenever something is observed that should be surprising (surprising to all those that are not already post-doctors in this area; again a stupid habit in other books of the "anthology" variety, like Atkins, Moore..., that just give you a wild array of topics, naturally RELATED, but in the books only slightly CONNECTED). Actually, often an observation is first presented, and then the situation is investigated - very beautiflly and simply.
- More advanced material is collected in boxes, but is still referred to, at later times, when appropriate.
- The authors have taken much trouble in presenting some "science philosophy", asking you to become aware of your own thinking process, and even questioning the habit of assuming correctness of our mind. I just love this.
- The introduction to Supramolecular Machines is extremely fascinating, BUT although it acts as a "carrot" for the reader to get through the earlier chapters, it is not so strongly connected with the rest of the book that it deserves mentioning in the title itself. I see this as "advertising" on the part of the authors for this area - which I do not criticize. This area (hard to define!) might well become as important as biotechnology.
*A WEAKNESS in course use: there are no unsolved exercises or problems. But somehow, exercises would have marred the fantastic coherence. This could be seen as the best HANDBOOK of the PRINCIPLES of physical chemistry ever in print - like the title says. Many short, self-contained chapters, with solved problems that are anything but routine... it's perfect. Anyone can use it - and enjoy its exciting style, simultaneously. *Other weaknesses: poor-quality pictures (but with good descriptions). Not very good index. Rotten binding, as always, these days: the book just falls apart, almost at once.
12 of 12 people found the following review helpful.
Yes, this is really an entirely fresh start for P-Chem!
By Ola Johannesson
This is, as Dr Bassi points out, really a new and modern book. It starts with Q.M. and introduces only formulas that are simple enough to be able to find use throughout the rest of the text. The whole book is just so coherent! The author knows all the time what you know, from following his book carefully, and pushes you all the time to your limit - but not beyond, as the mathematical derivations really are "neat". All other books are broken up into three major parts, between which there is only superficial connection. Here, the same equations govern every concept touched upon. It gives you a great feeling of satisfatcion and understanding! Overall, the book feels more like a novel, for its exciting style of writing and, again, continuity! (In spite of using very few words - this is definitely not the work of a graphoaniac!) If this is a textbook, then it sure is one of an all new breed... I look forwards to the next edition, with better binding and fewer misprints. And perhaps a supplementary volume with excercises, too. Get this book now! Even if you know this stuff, following the golden threads that the authors lay out, in a very personal and novel way, might let you experience some connections anew, or at least test your own skill agianst some unusual conclusions that pop ur here and there.
2 of 2 people found the following review helpful.
Kuhn's approarch to PChem
By Client X
I reviewed this book (and economy international edition) as a substitute for Atkins' PChem and this is what I can say:
IN GENERAL...
-Is superficial: it doesn't translate the results of the equations and calculations into a molecular interpretation or even a fully developed concept. Many of the formulas are not properly derived and just appear as an act of magic. It's one of those "what equation do I need to know" books instead of a "why chemical substances behave the way the do" book.
-It uses the micro-then-macro approach, and if you want to go the other way the book doesn't make it easy, since some classical themo concepts rely on understanding thermo stats.
-It develops "top science" topics within the book better than most.
-Probelms are OK but lack the real-life-application approach.
IN SPECIFIC...
-About Quantum: it presents the "real version" of the hydrogen orbitals (aka. general chemistry textbook forms) without going through the complex one (how else do you solve a centrosymmetric field problem?); it doesn't explain the meaning and real origin of quantum numbers (beyond GChem); it doesn't compare valence bond and molecular orbital theory and the concepts attached to each theory (and each theory alone); molecular spectroscopy is OK.
-About molecular thermodynamics: one chapter is not enough, sorry!
-About classical themodynamics: first law is not properly introduced (historical origin); enthalpy is presented as a given and not derived or its meaning explained; it doesn't describe the differences between heat and work; entropy is explained by Boltzmann's equation (good) but it's magically connected to Clausius' inequality instead of Prigogine's equality (hello, 20th century calling!); heat capacity and absolute entropy are not related to the structure and composition of matter; thermochemistry is very poorly developed, and the concept of combustion is not properly defined; irreversible procesess (the ones that happen in real world) are not properly treated; both free energy and equilibrium constants are not properly introduced and explained; real substances are not properly presented; the power of compressibility factor and Joule-Thomson coefficient are neglected; it doesn't deal with multicomponent phase diagrams and its application to extraction and distillation; non-ideal mixtures are only viewed as Debye-Hückel (which is not properly discussed).
-About "other" topics: it's great with electrochemistry, except it's not related to thermochemistry; surface chemistry is so poorly treated isotherms are nowhere to be seen; kinetics, polymers and proteins are more than OK.
IN CONCLUSION:
-I don't like it.
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